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For which process is ?S negative

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For which process is ?S negative?a AgCl (s) ? Ag (aq) Cl- (aq)b 2 KClO3 (s) ? 2 KCl (s) 3 O2 (g)c C3H8 (g) 5 O2 (g) ? 3 CO2 (g) 4 H2O (g)d Pb(NO3)2 (aq) 2 NH4Cl (aq) ? 2 NH4NO3 (aq) PbCl2 (s)

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that ?H°f of NO2(g) is 33.90
that result when E-3-methyl-3-hexene reacts with
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